Nyob rau hauv reimer tiemann cov tshuaj tiv thaiv dichlorocarbene ua li?

Cov txheej txheem:

Nyob rau hauv reimer tiemann cov tshuaj tiv thaiv dichlorocarbene ua li?
Nyob rau hauv reimer tiemann cov tshuaj tiv thaiv dichlorocarbene ua li?
Anonim

Nyob rau hauv cov tshuaj tiv thaiv Reimer Tiemann, cov dichlorocarbene ua raws li the electrophile. Dichlorocarbene yog ib hom reactive thiab nruab nrab uas muaj cov pa roj carbon divalent. Cov pa roj carbon tuav ib leeg ib khub ntawm ib qho hluav taws xob uas tuaj yeem muaj nyob hauv ib leeg lossis triplet xeev. Nws ua raws li electrophile.

Yam twg ntawm cov kab hauv qab no ua raws li Reimer Tiemann cov tshuaj tiv thaiv?

The dichlorocarbene yog:CCl2 siv ua electrophile (E+) hauv Reimer-Tiemann cov tshuaj tiv thaiv kom muab salicylaldehyde.

Reimer Tiemann cov lus teb piav qhia yog dab tsi?

: ob qho tib si ntawm cov tshuaj tiv thaiv zoo sib xws: a: cov tshuaj tiv thaiv rau kev tsim cov phenolic aldehydes los ntawm kev ua ntawm chloroform thiab caustic alkali ntawm phenols. b: cov tshuaj tiv thaiv rau kev tsim cov phenolic acids los ntawm carbon tetrachloride, alkali, thiab phenols.

Cov tshuaj tiv thaiv nruab nrab twg yog dichlorocarbene?

Dichlorocarbene yog ib qho nruab nrab hauv cov tshuaj tiv thaiv carbylamine. Hauv qhov kev hloov pauv no, cov tshuaj dichloromethane ntawm thawj amine yog kho nrog chloroform thiab aqueous sodium hydroxide nyob rau hauv lub xub ntiag ntawm catalytic npaum li cas ntawm theem-hloov catalyst.

Dab tsi yog qhov nruab nrab cuam tshuam nrog Reimer Tiemann cov tshuaj tiv thaiv?

Intermediate koom nrog Reimer-Tiemann cov tshuaj tiv thaiv yog a carbene.

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