Ntawm cov tshuaj tiv thaiv nrog hydroxylamine aldehydes tsim?

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Ntawm cov tshuaj tiv thaiv nrog hydroxylamine aldehydes tsim?
Ntawm cov tshuaj tiv thaiv nrog hydroxylamine aldehydes tsim?
Anonim

Hydroxylamine reacts nrog aldehydes thiab ketones los ua oximes, uas tau tham ntxiv hauv Tshooj 9.3.

Yuav ua li cas thaum aldehyde reacts nrog hydroxylamine?

Reaction ntawm aldehydes thiab ketones nrog hydroxylamine muab oximes. Lub nucleophilicity ntawm nitrogen ntawm hydroxylamine yog nce los ntawm lub xub ntiag ntawm cov pa. Kev hloov pauv proton ua tiav tso cai rau tshem tawm cov dej. Oximes feem ntau tsim ib qho sib xyaw ntawm geometric isomers.

Dab tsi yog cov khoom lag luam thaum acetaldehyde reacts nrog hydroxylamine?

Nyob rau hauv cov tshuaj tiv thaiv no, ib lub molecule ntawm acetaldehyde yog condensed nrog hydroxylamine los ua Acetaldoxime. Raws li cov tshuaj tiv thaiv no yog cov tshuaj tiv thaiv condensation, cov dej molecule raug tshem tawm.

Yuav ua li cas thaum hydroxylamine reacts nrog aldehydes thiab ketones muab sib npaug?

Hydroxylamine reacts nrog electrophiles, xws li alkylating agents, uas tuaj yeem txuas rau cov pa oxygen lossis nitrogen atoms: R-X + NH2OH → R-ONH 2 + HX. R-X + NH2OH → R-NHOH + HX. Cov tshuaj tiv thaiv ntawm NH2OH nrog ib qho aldehyde los yog ketone produces oxime.

Thaum aldehyde thiab ketone hnov mob nrog hydroxylamine ces qhov twg ntawm cov khoom hauv qab no tsim?

Yuav ua li cas aldehydes thiab ketones tuaj yeem hnov mob nrog hydroxylamine los tsim oximes lossis hydrazine los ua hydrazones.

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