Nyob hauv isobutane hyperconjugation koom nrog?

Cov txheej txheem:

Nyob hauv isobutane hyperconjugation koom nrog?
Nyob hauv isobutane hyperconjugation koom nrog?
Anonim

Nws feem ntau cuam tshuam nrog kev sib cuam tshuam ntawm cov hluav taws xob hauv lub sigma orbital nrog ze ze uas tsis yog-bonding p lossis antibonding σ∗ lossis π∗ orbitalstxhawm rau muab txuas ntxiv molecular orbitals uas ntxiv dag zog ntxiv. ntawm qhov system.

Yuav ua li cas ntawm cov orbitals hauv qab no koom nrog kev sib txuas lus?

Hyperconjugation suav nrog delocalization ntawm σ thiab π-bond orbitals, i.e, nws undrgoes σ-π conjugation. Hom delocalization cuam tshuam nrog sigma daim ntawv cog lus orbital yog hu ua hyperconjugation.

Puas hyperconjugation koom nrog delocalisation ntawm pi electrons?

Hyperconjugation yog the delocalisation ntawm sigma electron tseem hu ua sigma-pi conjugation. Kev tshwm sim ntawm α-H nrog rau ob daim ntawv cog lus, triple daim ntawv cog lus lossis cov pa roj carbon uas muaj cov nqi zoo (hauv carbonium ion) lossis umpaired electron (hauv dawb radical) yog ib qho mob rau hyperconjugation.

Yuav ua li cas hauv hyperconjugation?

Lub delocalization ntawm σ-electrons lossis ib khub ntawm electrons rau hauv π-orbital lossis p-orbital yog hu ua hyperconjugation. Nws tshwm sim vim overlapping ntawm σ-bonding orbital lossis lub orbital uas muaj ib leeg ib khub nrog nyob ib sab π-orbital lossis p-orbital. Nws tseem hu ua "tsis muaj daim ntawv cog lus" lossis "Baker-Nathan effect".

Thaum twg qhov tsis zoo Hyperconjugation tshwm sim?

Negative hyperconjugation tshwm sim thaum puv π lossis p orbitals cuam tshuam nrognyob ib sab antibonding σ orbitals(sib piv nrog "zoo" hyperconjugation raws li pom hauv ethyl carbocation). Ib qho piv txwv ntawm cov nyhuv no tuaj yeem pom hauv trifluoromethoxy anion thiab hauv cov nyhuv anomeric.

Pom zoo:

Nthuav cov khoom
Lo lus prosodically txhais li cas?
Nyeem ntxiv

Lo lus prosodically txhais li cas?

hais txog lub suab thiab lub suab (=txoj kev tus neeg hais lus lub suab nce thiab ntog) ntawm cov lus: Prosodic nta ua lub luag haujlwm tseem ceeb hauv kev tsim cov qauv kev ntxhov siab hauv cov lus thiab kab lus. prosodic teebmeem zoo li suab thiab intonation.

Vim li cas kuaj cov qib calcitonin?
Nyeem ntxiv

Vim li cas kuaj cov qib calcitonin?

Kev kuaj calcitonin feem ntau yog siv txhawm rau kuaj xyuas C-cell hyperplasia thiab medullary thyroid cancer medullary thyroid cancer Medullary carcinoma yuav xa mus rau ib qho ntawm ntau hom qog nqaij hlav ntawm epithelial keeb kwm. Raws li lo lus "

Thaum twg st sebastian raug ntaus?
Nyeem ntxiv

Thaum twg st sebastian raug ntaus?

Nws tau raug ntaus los ntawm Pope Benedict XIV hauv 1743 thiab canonized hauv 1807 los ntawm Pope Pius VII. Thaum twg Sebastian dhau los ua neeg dawb huv? St. 288, Rome [Italy]; Hnub ua koob tsheej Lub Ib Hlis 20), cov ntseeg thaum ntxov tau nrov los ntawm cov neeg pleev kob Renaissance thiab ntseeg tias tau tua neeg thaum muaj kev tsim txom ntawm cov ntseeg los ntawm Roman huab tais Diocletian.